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oxygen evolution reaction 11

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Reactive oxygen species 4

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oxygen vacancies 3

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Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygenelectrochemistry

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1550-1560 doi: 10.1007/s11705-021-2104-4

Abstract: between the carbon matrix and Co nanoparticles greatly enhance the electrocatalytic activity for the oxygenThe resulting Co@NC-0.86 exhibits a superb electrocatalytic activity for the oxygen reduction reaction

Keywords: cobalt embedment     N-doped carbons     covalent organic framework     oxygen reduction     Zn-air battery    

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 9,   Pages 1367-1376 doi: 10.1007/s11705-022-2153-3

Abstract: The exploration of efficient bifunctional electrocatalysts for oxygen reduction reaction and oxygen evolutionThe resultant Co2P/Ni3P@NC-0.2 enables an impressive electrocatalytic oxygen reductionMoreover, remarkable oxygen evolution reaction activity was also observed in alkaline conditions.This work not only describes a high-efficiency electrocatalyst for both oxygen reduction reaction andoxygen evolution reaction, but also highlights the application of metal phosphonate hybrids in fabricating

Keywords: metal phosphonate     cobalt/nickel phosphide     N-doped carbon     oxygen electrochemistry     Zn−air battery    

Research progress in tribo-electrochemistry and tribo-electrochemical polishing

ZHAI Wenjie

Frontiers of Mechanical Engineering 2007, Volume 2, Issue 4,   Pages 463-467 doi: 10.1007/s11465-007-0080-0

Abstract: In this paper, the status quo and recent progress in the research on tribo-electrochemistry in aqueous

Keywords: tribo-electrochemical mechanisms     planarization     non-aqueous     tribo-electrochemistry     summary    

Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

Frontiers of Mechanical Engineering 2012, Volume 7, Issue 1,   Pages 93-98 doi: 10.1007/s11465-012-0313-8

Abstract: There were significant differences in the tribological and electrochemistry properties of the rubbing

Keywords: hydrogen peroxide     wear     corrosion     wear mechanism    

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reductionand oxygen evolution reaction: a density functional theory study

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 5,   Pages 570-580 doi: 10.1007/s11705-022-2247-y

Abstract: The oxygen reduction reaction and oxygen evolution reaction catalytic activities of heterometallic cluster-basedAmong all heterometallic clusters, Fe2Mn–Mn has a minimum overpotential of 0.35 V for oxygenreduction reaction, and Fe2Co–Co possesses the smallest overpotential of 0.32 V for oxygen

Keywords: bimetallic metal–organic frameworks     bifunctional electrocatalyst     density functional theory     oxygenreduction reaction     oxygen evolution reaction    

Interface engineering for enhancing electrocatalytic oxygen evolution reaction of CoS/CeO heterostructures

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 3,   Pages 376-383 doi: 10.1007/s11705-021-2062-x

Abstract: renewable energy conversion, it is important to develop low-cost and high-efficiency electrocatalyst for oxygen

Keywords: interface engineering     CoS/CeO2     electrodeposition     electrocatalyst     oxygen evolution reaction    

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

Frontiers in Energy doi: 10.1007/s11708-023-0892-6

Abstract: entropy materials (HEMs) have developed rapidly in the field of electrocatalytic water-electrolysis for oxygen

Keywords: high-entropy     electrocatalysis     synthetic methods     water-electrolysis     hydrogen and oxygen evolutions    

A review of Pt-based electrocatalysts for oxygen reduction reaction

Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 268-285 doi: 10.1007/s11708-017-0466-6

Abstract: Development of active and durable electrocatalyst for oxygen reduction reaction (ORR) remains one challenge

Keywords: oxygen reduction reaction (ORR)     electrocatalysis     platinum catalyst     activity     durability    

Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 2,   Pages 226-235 doi: 10.1007/s11705-022-2198-3

Abstract: Prussian blue and its analogs are extensively investigated as a cathode for ammonium-ion batteries. However, they often suffer from poor electronic conductivity. Here, we report a Ni2Fe(CN)6/multiwalled carbon nanotube composite electrode material, which is prepared using a simple coprecipitation approach. The obtained material consists of nanoparticles with sizes 30–50 nm and the multiwalled carbon nanotube embedded in it. The existence of multiwalled carbon nanotube ensures that the Ni2Fe(CN)6/multiwalled carbon nanotube composite shows excellent electrochemical performance, achieving a discharge capacity of 55.1 mAh·g–1 at 1 C and 43.2 mAh·g–1 even at 15 C. An increase in the ammonium-ion diffusion coefficient and ionic/electron conductivity based on kinetic investigations accounts for their high performance. Furthermore, detailed ex situ characterizations demonstrate that Ni2Fe(CN)6/multiwalled carbon nanotube composite offers three advantages: negligible lattice expansion during cycling, stable structure, and the reversible redox couple. Therefore, the Ni2Fe(CN)6/multiwalled carbon nanotube composite presents a long cycling life and high rate capacity. Finally, our study reports a desirable material for ammonium-ion batteries and provides a practical approach for improving the electrochemical performance of Prussian blue and its analogs.

Keywords: nickel ferrocyanides     NH4+     electrochemistry     Prussian blue     aqueous ammonium ion    

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1937-1948 doi: 10.1007/s11705-023-2353-5

Abstract: In this study, Bi2MoO6 with adjustable rich oxygen vacancies was prepared by aThe experiment results show that Bi2MoO6 with rich oxygen vacancies is an excellentThe results display that the band energy of the samples with oxygen vacancies was narrowed and the lightTherefore, this work provides a convenient and efficient method to prepare potential adjustable oxygen

Keywords: Bi2MoO6     oxygen vacancies     photoreduction     Cr(VI)     RhB    

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 3,   Pages 326-333 doi: 10.1007/s11705-022-2213-8

Abstract: In this study, a new graphene role (oxygen vacancy inducer) in graphene/oxides composites anodes, whichgraphene forms carbon vacancies due to increased thermal vibration, and the carbon vacancies capture oxygenatoms, facilitating the formation of oxygen vacancies in oxides.Moreover, the induced oxygen vacancy concentrations can be regulated by sintering temperatures, and theAccording to density functional theory calculations and electrochemical measurements, the oxygen vacancies

Keywords: oxide     oxygen vacancy     graphene     anode     density functional theory calculation    

Multivalent manganese oxides with high electrocatalytic activity for oxygen reduction reaction

Xiangfeng Peng, Zhenhai Wang, Zhao Wang, Yunxiang Pan

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 4,   Pages 790-797 doi: 10.1007/s11705-018-1706-y

Abstract: The prepared catalyst shows a higher electrocatalytic activity towards the oxygen reduction reactionenhanced activity could be due to the coexistence of manganese ions with different valences, the higher oxygen

Keywords: oxygen reduction reaction     manganese oxides     mixed valences of manganese     oxygen adsorption     dielectric barrier    

Cooperative effect between copper species and oxygen vacancy in CeZrCuO catalysts for carbon monoxide

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1524-1536 doi: 10.1007/s11705-021-2106-2

Abstract: Thus, the number of oxygen vacancies caused by the Cu2+ entering the lattice (e.g., Cu2+–□–Ce4+; □: oxygen vacancy), and the amount of reducible copper species caused byCatalytic CO oxidation tests indicated that the oxygen vacancy and the reducible copper species wereThus, the samples x = 0.1 and 0.3, which possessed the most oxygen vacancy or reducible copper

Keywords: Ce–Zr–Cu–O     CO oxidation     reducible copper species     oxygen vacancy     cooperative effect    

Enhanced performance of oxygen vacancies on CO adsorption and activation over different phases of ZrO

Frontiers in Energy 2023, Volume 17, Issue 4,   Pages 545-554 doi: 10.1007/s11708-023-0867-7

Abstract: The effect of oxygen vacancies on the adsorption and activation of CO2 on the surface of differentThe calculations show that the oxygen vacancies contribute greatly to both the adsorption and activationt-ZrO2 and, m-ZrO2 surfaces is enhanced to 5, 4, and 3 folds with the help of oxygenFurthermore, the activation of CO2 on the ZrO2 surface where oxygen vacancies areThis finding demonstrates that the presence of oxygen vacancies promotes the activation of CO2

Keywords: CO2 activation     oxygen vacancies     ZrO2     different phases    

Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition

Frontiers in Energy doi: 10.1007/s11708-023-0898-0

Abstract: Electrocatalytic CO2 reduction (ECR) offers an attractive approach to realizing carbon neutrality and producing valuable chemicals and fuels using CO2 as the feedstock. However, the lack of cost-effective electrocatalysts with better performances has seriously hindered its application. Herein, a one-step co-electrodeposition method was used to introduce Zn, a metal with weak *CO binding energy, into Cu to form Cu/Zn intermetallic catalysts (Cu/Zn IMCs). It was shown that, using an H-cell, the high Faradaic efficiency of C2+ hydrocarbons/alcohols (FEC2+) could be achieved in ECR by adjusting the surface metal components and the applied potential. In suitable conditions, FEC2+ and current density could be as high as 75% and 40 mA/cm2, respectively. Compared with the Cu catalyst, the Cu/Zn IMCs have a lower interfacial charge transfer resistance and a larger electrochemically active surface area (ECSA), which accelerate the reaction. Moreover, the *CO formed on Zn sites can move to Cu sites due to its weak binding with *CO, and thus enhance the C–C coupling on the Cu surface to form C2+ products.

Keywords: carbon dioxide electroreduction     electrochemistry     co-electrodeposition     intermetallic catalysts     value-added    

Title Author Date Type Operation

Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygenelectrochemistry

Journal Article

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen

Journal Article

Research progress in tribo-electrochemistry and tribo-electrochemical polishing

ZHAI Wenjie

Journal Article

Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

Journal Article

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reductionand oxygen evolution reaction: a density functional theory study

Journal Article

Interface engineering for enhancing electrocatalytic oxygen evolution reaction of CoS/CeO heterostructures

Journal Article

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

Journal Article

A review of Pt-based electrocatalysts for oxygen reduction reaction

Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG

Journal Article

Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

Journal Article

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

Journal Article

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

Journal Article

Multivalent manganese oxides with high electrocatalytic activity for oxygen reduction reaction

Xiangfeng Peng, Zhenhai Wang, Zhao Wang, Yunxiang Pan

Journal Article

Cooperative effect between copper species and oxygen vacancy in CeZrCuO catalysts for carbon monoxide

Journal Article

Enhanced performance of oxygen vacancies on CO adsorption and activation over different phases of ZrO

Journal Article

Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition

Journal Article